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The G values for the products (right side of the equation) are summed and the G values f f for the reactants (left side of the equation) are subtracted, taking care to ensure that the arithmetic signs are correct. Biochemical reactions under physiological conditions (for microbiologists) For evaluations of changes of free energy under actual physiological conditions, many assumptions made by chemists are not really relevant. Under environmentally relevant conditions, the concentrations of substrates and products are not 1 M and the partial pressures are not 1 atm. One way to compensate for deviations from standard conditions is to adjust calculations according to the Nernst equation, because the change in Gibbs free energy values of a reaction are directly linked to its equilibrium constant. This is re ected in G values. For a hypothetical reaction: aA + bB cC + dD G values are calculated by using the mass equation: G = G + RT ln [C]c[D]d/[A]a[B]b where R is a constant (8.29 J/mol/ K) and T is temperature in K. Under dynamic biological conditions that feature very low concentrations of some reactants and products, free energy yields can shift drastically from those predicted under standard conditions. birt pdf 417 Eclipse BIRT PDF417 Barcode Maker add-in makes PDF417 ...
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